Synthesis of Some Carboxylic Acid Analogs Cleaved between the C-2 and C-3 Bond of Tetramethylcyclopropanecarboxylic Acid, and Insecticidal Activities of Their Esters

Akimichi FURUHATA; Masachika HIRANO; Izumi FUJIMOTO; Masanao MATSUI

doi:10.1271/bbb1961.51.1633

Agricultural and Biological Chemistry

Online ISSN : 1881-1280
Print ISSN : 0002-1369
ISSN-L : 0002-1369

Synthesis of Some Carboxylic Acid Analogs Cleaved between the C-2 and C-3 Bond of Tetramethylcyclopropanecarboxylic Acid, and Insecticidal Activities of Their Esters

Akimichi FURUHATA, Masachika HIRANO, Izumi FUJIMOTO, Masanao MATSUI

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JOURNAL FREE ACCESS

1987 Volume 51 Issue 6 Pages 1633-1640

DOI https://doi.org/10.1271/bbb1961.51.1633

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Abstract

Carboxylic acids with a cleaved type of cyclopropane ring between the C-2 and C-3 bond in tetramethylcyclopropanecarboxylic acid, the acid part of fenpropathrin, were prepared. Several of their esters with pyrethroidal alcohols exhibited good insecticidal activity, but their activity was a little weaker than that of fenpropathrin.

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