1989 Volume 53 Issue 1 Pages 37-40
Optically pure pahutoxin and its antipode were synthesized from (S)- and (R)-3-hydroxyhexadecanoic acids, which were obtained by the enantio-differentiating hydrogenation of methyl 3-oxohexadecanoate over asymmetrically modified Raney nickel catalyst. By an optical correlation with synthetic materials, dextrorotatory natural pahutoxin was determined to be of (S)-configuration.
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