Synthesis of (S)-13-Hydroxy (2E, 4E, 8E)- and (2E, 4E, 8Z)-Tetradecatrienoic Acids
1995 年 59 巻 6 号 p. 1032-1035
詳細
1995 年 59 巻 6 号 p. 1032-1035
The syntheses of (S)-13-hydroxy-(2E, 4E, 8E)-tetradecatrienoic acid (1) and (2E, 4E, 8Z-tetradecatrienoic acid (2) were carried out by using the Wittig reaction as the key step. The asymmetric center at C-13 and the double bond between C-8 and C-9 for natural compound 1 were reconfirmed as being of (S) configuration and E, respectively. The relationship between the structure of the unsaturated hydroxy fatty acids and their inhibitory effect on the growth of lettuce was investigated.
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