Synthesis of the Esterified Cerebroside in the Epidermis of Guinea Pigs
1995 年 59 巻 9 号 p. 1644-1647
詳細
1995 年 59 巻 9 号 p. 1644-1647
(2S, 3R, 4E, 23'Z)-1-O-(β-D-Glucopyranosyl)-N-(32'-linoleoyloxy-23'-dotriacontenoyl)-4-sphingenine (1), a component of the esterified cerebrosides in the epidermis of guinea pigs, was synthesized by selective N-acylation of (2S, 3R, 4E)-1-O-(β-D-glucopyranosyl)-4-sphingenine (18) with activated ω-linoleoyloxy fatty acid ester 17.
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