木更津工業高等専門学校紀要
Online ISSN : 2188-921X
Print ISSN : 2188-9201
ISSN-L : 0285-7901
2,6-ジメチル-3-ヘプチン-2,6-ジオールの水添分解
漆間 伸司
著者情報
研究報告書・技術報告書 フリー

1986 年 19 巻 p. 97-100

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抄録
Catalytic hydrogenation of 2,6-dimethyl-3-heptyne-2,6-diol under ordinary pressure and temperature resulted hydrogenolysis products, the amount of which was about half mole of used diol. By means of IR, NMR and others, the hydrogenolysis product was identified with 2,6-dimethyl-2-heptanol which synthesized from methylheptanone. It was infered from the NMR spectrogram of the hydrogenolysis product of 2,6-dimethyl-3-heptyne-2,6-diol-d6 that elimination of OH group takes place in similar ratio on the OH group of 2 and 6 position.
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© 1986 独立行政法人 国立高等専門学校機構 木更津工業高等専門学校
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