分析化学
Print ISSN : 0525-1931
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トリアルキル (1-インデニル) 化合物の1H-及び13C-NMR化学シフト
吉田 隆一菅野 智恵子齋藤 真也永田 親清
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2001 年 50 巻 8 号 p. 553-557

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The 1H- and 13C-NMR spectra of the trimethyl (1-indenyl) carbon (IV) compound were measured. Assignments of the chemical shifts for 1H and 13C in this compound were obtained by means of hydrogen-hydrogen nuclear Overhauser effect spectroscopy (H-H NOESY), hydrogen-hydrogen correlation spectroscopy (H-H COSY) and carbon-hydrogen correlation spectroscopy (C-H COSY). The 13C chemical shifts of the methyl and C1 carbons were correlated with the electronegativity of the central elements: C, Si, Ge and Sn, of the (CH3)3C(C9H7), (CH3)3Si(C9H7), (CH3)3Ge(C9H7) and (n-C4H9)3Sn(C9H7) compounds.
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© The Japan Society for Analytical Chemistry 2001
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