分析化学
Print ISSN : 0525-1931
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表面電離型質量分析計に用いられるフィラメントの表面状態のウラン同位体比測定に及ぼす影響
田口 茂郎宮内 啓成堀籠 和志山本 昌彦久野 剛彦
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2018 年 67 巻 11 号 p. 681-686

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Prior to the coating of a sample to a filament surface, a Joule-heating treatment of the filament was performed to remove any impurities from the filament and to minimize the influence of the background in thermal ionization mass spectrometry. In this work, the effect of the surface condition of the tungsten filament induced by the Joule-heating treatment on an uranium isotopic (235U/238U) measurement has been investigated. By the Joule-heating treatment, crystal grains were formed on the filament surface, and the filament surface became smooth. It was found that by extending the Joule-heating time, the surface became smoother and the precision of uranium isotopic (235U/238U) measurement was improved.

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© 2018 The Japan Society for Analytical Chemistry
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