The Spectroscopic Study on the Chemical State at Pd/Mg Interface

Abstract

The chemical state of interface between Pd and Mg layers has been investigated by XPS and NEXAFS methods. Since it is thought that the hydrogen storage ability strongly depends on the chemical state of the interface, we focus on the interface of the Pd—Mg. It is found that the different phase from bulk metal or oxide exists between Pd and Mg layers prepared by both DC magnetron sputtering and vacuum evaporation methods. From XPS and NEXAFS measurements, we have revealed that Pd loses the electron and Mg picks up one in this phase. It might be thought that the Pd—Mg alloy phase exists between Pd and Mg. [DOI: 10.1380/ejssnt.2011.438]