Proceedings of Japanese Liquid Crystal Society Annual meeting
Online ISSN : 2432-5988
Print ISSN : 1880-3490
ISSN-L : 1880-3490
2012 Japanese Liquid Crystal Conference
Session ID : PA42
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PA42 Deformation Analysis of Crosslinked Azobenzene Liquid-Crystalline Polymer Films with Surface Labeled Gratings
*Norihisa AKAMATSUJun-ichi MAMIYAMotoi KINOSHITAAtsushi SHISHIDO
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Abstract

Azobenzene derivative, azobenzene crosslinker, phenylbenzoate derivative and hydroquinone crosslinker with vinyl groups were synthesized to fabricate the crosslinked liquid-crystalline polymer films. Undirectionally aligned crosslinked azobenzene liquid-crystalline polymer films with a polysiloxane backbone were prepared by hydrosilylation reaction. Two-dimensional surface labeled gratings were recorded in surface of the film with a photomask. A probe beam at 633 nm was incident to the film, and surface deformation of the film was evaluated by an external stress or ultraviolet irradiation using a light diffraction. In addition, effect of position and behavior of front and back surfaces in the film on the deformation has been investigated.

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© 2012 Japanese Liquid Crystal Society
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