棒状分子溶液のぬれ転移

抄録

We discuss on first-wetting transition from partial to complete wetting near a wall in solutions of rigid-rod-like molecules. Based on the Cahn's construction for the free energy of a surface and Flory theory for hard rods, we caluculate the intrefacial tension, the adsorption amounts and the contact angle as a function of temperature and the adsorption energy.