Electrochemistry
Online ISSN : 2186-2451
Print ISSN : 1344-3542
ISSN-L : 1344-3542
Communications
Inhibition of the Dissolution of Fe from Fe–Pt Nano Particles by a Structural Phase Transitions
Takashi ITOHMasaki UEBAYASHIKazuyuki TOHJIBalachandran JEYADEVAN
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2010 Volume 78 Issue 2 Pages 157-160

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Abstract
Fe–Pt nanoparticles fabricated by the polyol process have been reported as a possible alternative material for use in catalytic electrodes for polymer electrolyte fuel cells (PEFCs). Catalytic Fe–Pt alloys suffer from a problem where Fe dissolves from the alloy. Here, we examined the dissolution of Fe into the electrolyte for various composition ratios of Fe to Pt. We have also described the characteristics of Fe–Pt nanoparticles on the basis of XRD, XRF, TEM-EDX and electrochemical measurements and have discussed the rinse effect of Fe–Pt nanoparticles in acid solutions and the annealing effect of Fe–Pt caused by structural phase transitions from disordered fcc to ordered fct phase structures.
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© 2010 The Electrochemical Society of Japan
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