2010 Volume 78 Issue 5 Pages 387-389
Solid polymer electrolytes, the electrolytes without a flammable solvent, can solve a safety problem of rechargeable lithium (Li) batteries. We prepared poly(oxetane) with nitrile groups, P(CYAMEO), by ring-opening polymerization of the oxetane derivative and used it for a matrix of solid polymer electrolytes. Charge-discharge performance of the Li|P(CYAMEO)-based electrolyte|LiCoO2 cells was tested under constant current charge-discharge cycling condition. The test cells with the P(CYAMEO)-based electrolyte that contained LiN(CF3SO2)2, showed better discharge performance than those with the electrolytes that contained other Li salts. The polarization behaviors of the Li electrode in the electrolyte suggest that performance of the test cells partially depend on the structure of the solid electrolyte interphase on the Li electrode surface in the P(CYAMEO)-based electrolyte.