繊維学会誌
Online ISSN : 1884-2259
Print ISSN : 0037-9875
難染性繊維染色の研究
第14報 リンーモリブデン,タングステン処理について
山田 仁穂四宮 知郎
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ジャーナル フリー

1960 年 16 巻 8 号 p. 653-656

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The effect of temprature on the absorption of M0 or W by vinylon, 6-nylon or wool, and the chemical structure of the complex acid absorbed by vinylon or 6-nylon are studied.
1) The velocity of absorption of M0 or W by vinylon, 6-nylon and wool is temperature dependent, but the rate of absorption curves from a finite bath leading to some equilibrium absonption independently of temperature.
2) Where the gram atom total of M0 and P is constant, it shows the maximum absorption of M0 by vinylon at the ratio of M0 to P is 3:1 in complex acid solution.
3) At the constant concentration of M0, the absorption of M0 and P by vinylon or 6-nylon appears to increase with increasing the concentration of P, with an upper limit of around the ratio of M0:P; 3:1 in complex acid solution, and in the this equilibrium absorption on fiber, the ratio of M0:P shows 12:1, which suggests the molecular structure of the complex acid is 3H2O•P2O5•24•M0O3.
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