巻号一覧
16 巻, 8 号
選択された号の論文の14件中1～14を表示しています
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大岡 忠三1960 年 16 巻 8 号 p. 607-611
発行日: 1960/08/10
公開日: 2008/11/28
ジャーナル フリーPDF形式でダウンロード (513K) -
第XXXIV報 逆転ロール式フェルト試験機の試作とその性能池田 佐喜男1960 年 16 巻 8 号 p. 612-616
発行日: 1960/08/10
公開日: 2008/11/28
ジャーナル フリーIn order to compare the feltability of the variously carroted furs, an apparatus was constructed and its accuracy was examined. The felting action was given by rubbing a sample between two rollers whose rolling can be reversed automatically in the opposite direction. The good reproducibility was proved by the experiments.抄録全体を表示PDF形式でダウンロード (1169K) -
辻 和一郎, 今井 政三, 松崎 健一, 松本 篤二1960 年 16 巻 8 号 p. 617-621
発行日: 1960/08/10
公開日: 2008/11/28
ジャーナル フリーThe mechanism of the softening action of the textile oiling agent is discussed based on the evaluation of torsional rigidity, coefficient of friction and Young_??_s modulus.
Torsional rigidity is evaluated from following formula.
T: moment of torsion (kg_??_mm)
G: rigidity of phosphor bronze wire (kg/mm2)
l: length of phosphor bronze wire (mm)
D: diameter of phosphor bronze wire (mm)
θ: torsion angle of indicator (degree)
The following formula is derived from the above formula
where K: constant
The torsional rigidity in this experiment is estimated from the relation between θ and the number of torsion of the sample.
The shearing stress (T′) was calculated from the following formula.
where d: diameter of sample (mm)
Torsional rigidity of raw silk decreases markedly by treating with some oiling agents. Similar result is observed with 6 Nylon (Amilan) monofilament in less degree.
In the case of viscose rayon, torsional rigidity of multifilament yarn decreases by treating with oiling agents, but this appears attributable to the decrease of the coefficient of friction, because the torsional rigidity of viscose monofilament is never affected by oiling agent.抄録全体を表示PDF形式でダウンロード (331K) -
第14報 X線による延伸糸の結晶化度の測定高橋 正夫, 温品 恭彦1960 年 16 巻 8 号 p. 622-627
発行日: 1960/08/10
公開日: 2008/11/28
ジャーナル フリーThe intencity distribution curves of X-ray diffractions along lines radiating from the center of the photograph at definite angles to the equator for various drawn filaments were measured by the apparatus of Geiger counter type. If the scattering intensities due to non-crystalline parts at definite 2 θ were constant along the circular lines, the minimum values among the measured intensities along the circular line at definite 2 θ should correspond to the intensities of non-crystalline parts. The Bragg reflextions above the background in a rotation photograph (powder photograph) and the background which is divided as discribed above were taken as the indexes of crystalline and noncrystalline scattering respectively. This estimation of crystallinities of drawn filaments is used for these samples whose degrees of orientation are almost of the same values.
By this method, the crystallinities of several samples are estimated, and at the same time the degrees of orientation and of the widths of half values are observed,
As the contents of copolymerized component in AN copolymers increased, the crystallinity become lower. As the heat treatment temperature of PAN become higher, the crystallinity and the lateral order increase.
The equatorial and meridional small-angle scattering curves for the drawn filaments heat-treated at various temperatures have no maxima and there are therefore no large identity periods in these samples. The statistical distribution maximum of the distance between crystallites calculated by the Kratky's theory become larger with the heat-treatment temperature up to 160°C.抄録全体を表示PDF形式でダウンロード (1293K) -
第15報 単独溶媒についての検討高橋 正夫, 渡辺 正元1960 年 16 巻 8 号 p. 628-632
発行日: 1960/08/10
公開日: 2008/11/28
ジャーナル フリーThe acrylonitrile-methyl acrylate copolymer (content of methyl-acrylate 3_??_5 mol%) was dissolved in those solvents which are shown below and these polymer-solvent systems did not gel at room temperature for remarkably long period.
β-Propiolactone γ-Butyrolactone Dimethylsulfoxide (DMSO) Tetramethylene sulfoxide Tetramethylene sulfone DMF DMA N-Formylmorphorine N-Acetylmorphorine N-Acetylpyrrolidine Glyconitrile
The viscosities and viscosity stabilities of the AN polymer concentrated solutions in Y-butyrollactone, DMSO, DMF and DMA, whose prices are relatively low, may be used for spinning solution.抄録全体を表示PDF形式でダウンロード (393K) -
是松 幹雄, 増田 坦, 栗山 捨三1960 年 16 巻 8 号 p. 633-638
発行日: 1960/08/10
公開日: 2008/11/28
ジャーナル フリーIn studying the thermal shrinkage of polyethylene oxybenzoate (PEOB), (-CO-_??_-O-CH2-CH2-_??_-O-)n;, fibers made by melt-spinning and drawing, following results have been obtained.
(1) At elevated temperatures, PEOB fibers tend to shrink to a larger extent compared with those from the other crystalline polymers.
(2) The shrinkage takes place very rapidly and is affected mainly by the rate of heating, not by the heating media.
(3) The shrinking tendency or force required to prevent shrinking of PEOB fibers is usually higher than commercial 6-nylon and polyethylene terephthalate fibers.
(4) PEOB fibers can be stabilized by heat treatment for a short time without being allowed to contract at elevated temperatures, and after the treatement no remarkable deterioration of their fiber-properties has been observed.
(5) Crystallization by the heat treatment and the transition of the crystal structure by thermal shrinkage have been ascertained by the interpretation of the X-ray diffraction patterns.
The changes of the molecular configuration by the thermal shrinkage and the stabilization by the heat treatment are discussed.抄録全体を表示PDF形式でダウンロード (1466K) -
吉村 三郎1960 年 16 巻 8 号 p. 639-642
発行日: 1960/08/10
公開日: 2008/11/28
ジャーナル フリーIn order to simplify the determination of KW as an evaluation of dissolving grade pulp (DP), emulsion xanthation has been applied, since it is simpler and has better reproducibility than the ordinary vapor phase xathation method. An apparatus (Fig. 1) was designed and correlation between KW by emulsion and ordinary xanthation was obtained (Fig. 2).
The apparatus consists of a body and a top cover, and they made two cylinderical rooms connecting through narrow slit (clearence 1.5cm). Each room has a stirring wing whirling at 90° phase difference. As the results of various experiments on behavior of the reaction mixture in process of emulsion xanthation by the above apparatus, it has been found that the following conditions are bearable;
Pulp consistency 7%, NaOH concentration 13%, CS2 60% for pulp, temperature at xanthation 20° ± 1°C, xanthating time 3 hrs., final viscose composition (diluted by water) cellulose 5.8%, alkali 10.0%.
Reproducibility of KW value by this emulsion xanthation method is good, as seen from Tab. 1, in which KW values are measured five times on the same sulfite DP. A nearly linear relationship between KW values by emulsion xanthation and vapor phase xanthation (Japanese Industrial Standard Method) is obtained on five commercial sulfite DPs (Fig. 2). Further, developing better apparatus and viscose preparation condition is under investigation.抄録全体を表示PDF形式でダウンロード (293K) -
第1報 制御対象としてのローラドラフトの動特性について(I)井原 素三, 赤見 仁, 高木 節雄1960 年 16 巻 8 号 p. 643-647
発行日: 1960/08/10
公開日: 2008/11/28
ジャーナル フリーAlthough there are many studies on the automatic control of sliver thickness, contorolable variations are generally of “long period” and the control of “short period” variation is left intact.
In case of controlling “short period” variation it becomes impossible to ignore the influence of the fiber length in slivers and improcessing this factor would have important becomings are obtained.
in this study, the theoretical process character of roller-drafting is made and the following results:-
(1) The differential equation in the unsteady roller-drafting is;
(2) When the variation is small, the transfer function between the surface velocity of front roller and produced sliver thickness is;
G1(s)=k1/(1+T1s)
(3) The transfer function between the thickness of the feed and produced sliver is
G2(s)=k2(1-T2s)/(1+T1s)
(4) Each quantity in roller-drafting coresponds to the one in automatic control in the following way:-
Potential sliver thickness
Flow Fiber flow
Capacitance Fiber quantity of taft-diagram per unit sliver thickness.
Resistance Reciprocal of the surface velocity of roller
(5) The transfer function of front roller is 1/(1+T1s) and of back roller (1-T2s)抄録全体を表示PDF形式でダウンロード (314K) -
黒崎 新也, 近田 富士雄1960 年 16 巻 8 号 p. 648-652
発行日: 1960/08/10
公開日: 2008/11/28
ジャーナル フリーBy using the tester in our preceding papar (I), the degree and the profile of tension generated under a variety of spinning conditions are investigated.
1. p, c and f in Fig. 5 are explained as follows,
p: preliminary time, when the tension develops monotonus until critical point.
c: critical point.
f: formative time, when the tension makes various profiles shown in Fig. 4 and Fig. 5.
2. As the draft ratio, or spindle revolution becomes higher, the critical tension becomes larger.(Fig.6, Fig.7, Fig.8)
3. When the spindle revolution is high or low, the degree of descent in formative tension is large, and when intermediate it is small. And as the draft ratio becomes high, the degree of descent becomes large. (Fig. 9, Fig. 10)抄録全体を表示PDF形式でダウンロード (336K) -
第14報 リンーモリブデン,タングステン処理について山田 仁穂, 四宮 知郎1960 年 16 巻 8 号 p. 653-656
発行日: 1960/08/10
公開日: 2008/11/28
ジャーナル フリーThe effect of temprature on the absorption of M0 or W by vinylon, 6-nylon or wool, and the chemical structure of the complex acid absorbed by vinylon or 6-nylon are studied.
1) The velocity of absorption of M0 or W by vinylon, 6-nylon and wool is temperature dependent, but the rate of absorption curves from a finite bath leading to some equilibrium absonption independently of temperature.
2) Where the gram atom total of M0 and P is constant, it shows the maximum absorption of M0 by vinylon at the ratio of M0 to P is 3:1 in complex acid solution.
3) At the constant concentration of M0, the absorption of M0 and P by vinylon or 6-nylon appears to increase with increasing the concentration of P, with an upper limit of around the ratio of M0:P; 3:1 in complex acid solution, and in the this equilibrium absorption on fiber, the ratio of M0:P shows 12:1, which suggests the molecular structure of the complex acid is 3H2O•P2O5•24•M0O3.抄録全体を表示PDF形式でダウンロード (275K) -
第15報 チオインドカルボン酸類-芳香族ニトロソ化合物系縮合染料について山田 仁穂1960 年 16 巻 8 号 p. 656-661,653
発行日: 1960/08/10
公開日: 2008/11/28
ジャーナル フリーBy applying, the condensation-reaction of thioindoxylcarboxylic acids (Sx) with aromatic nitroso compounds (Nx), many synthetic fibers were dyed deeply.
The suitable components of the aromatic nitroso components are NB, N5, N6 and N7.
Of the thioindoxylcarboxylic acids, at the point of deep color and fastness, the order are; S3>S2>S1, at the reactivity, thus; S1>S2>S3.
The best dyeing of these fibers are different respectively, but in general, the dyeing by Sx is effective for the first component in neutral or acid solution.
Saran is dyed most deeply and fastly. Perlon, 6-nylon, and also by using some carrier, terylen and acrylonitrile fibers are dyed deeply well, but they have no practical use, because of their low light-fastness.抄録全体を表示PDF形式でダウンロード (550K) -
第10報 モノアゾ色素の吸収曲線変化について石井 美治1960 年 16 巻 8 号 p. 662-667
発行日: 1960/08/10
公開日: 2008/11/28
ジャーナル フリーThe dye components, Fast Orange GC, Red B, Red RL, Bordeaux GP and Scarlet G, and the other components, Naphthol AS and β-Naphthol, were purified. By combinations between these components colors were developed in the cellophane and PVA sheets. The changes of visible absorption spectra of the dyes in the films obtained after steaming, soaping and boiling in water, respectively, were compared with those of before the treatments. The Naphthol AS dyes revealed following spectral changes through the above treatments:
(a) the maxima of the absorption bands of Orange GC, Bordeaux GP and Scarlet G showed no change, (b) those of Red RL shifted to the long wave length side, (c) those of Red B to the short side. In all cases, the optical densities increased by the treatments. The shape of the absorption curves after the treatments were restored to their original ones, when the dyes are dry heated at about the melting points of the dyes, i.e. 250_??_300°C.
These spectral changes by the wet or dry heating may be due to aggregation or dispersion of the color lakes in the films.抄録全体を表示PDF形式でダウンロード (372K) -
第5報 加熱処理の検討矢島 幹晴, 荒川 清1960 年 16 巻 8 号 p. 668-672
発行日: 1960/08/10
公開日: 2008/11/28
ジャーナル フリーThe authors finished the viscose-rayon fiber by the melamine resin and thereby examined the condition of curing with the following results;
(1) Temperature and time of curing affect much the tensile recovery of resin treated fiber, but less its tensile strength, elongation, knot strength, bending rigidity and water imbibition.
(2) Higher tensile recovery, higher bending rigidity, lower water imbibition and lower knot strength were always observed with the fiber which is finished by the method of steam curing than with that by the method of dry curing.抄録全体を表示PDF形式でダウンロード (320K) -
上平 恒1960 年 16 巻 8 号 p. 673-677
発行日: 1960/08/10
公開日: 2008/11/28
ジャーナル フリーPDF形式でダウンロード (430K)
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