GEOCHEMICAL JOURNAL
Online ISSN : 1880-5973
Print ISSN : 0016-7002
ISSN-L : 0016-7002
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High-precision in situ analysis of Pb isotopes in melt inclusions by LA-ICP-MS and application of Independent Component Analysis
Morihisa HamadaJun-Ichi KimuraQing ChangTakeshi HanyuTakayuki UshikuboKenji ShimizuMotoo ItoTakahiro OzawaHikaru Iwamori
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2018 年 52 巻 1 号 p. 69-74

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We report a high-precision 206Pb-based lead isotope composition of olivine-hosted melt inclusions in basaltic rocks from Rarotonga Island, Polynesia, in the southern Pacific, using femtosecond laser ablation (FsLA)-multiple Faraday collector-inductively coupled plasma-mass spectrometry (MFC-ICP-MS). This improved method enables high-precision analysis of Pb isotopes from low-Pb (≤10 ppm) melt inclusions with a crater size of ~30 μm in diameter and depth. The small crater size allows for further analysis of major and trace elements from the same melt inclusions using FsLA-sector field (SF)-ICP-MS. Using Pb isotope ratios of two olivine-hosted melt inclusions, we suggest that the mantle source beneath Rarotonga Island is heterogeneous. Such identification becomes possible owing to high-precision in situ analysis of Pb isotopes in melt inclusions and application of statistical approaches such as Independent Component Analysis to the analytical data.

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© 2018 by The Geochemical Society of Japan
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