GEOCHEMICAL JOURNAL
Online ISSN : 1880-5973
Print ISSN : 0016-7002
ISSN-L : 0016-7002
最新号
選択された号の論文の1件中1~1を表示しています
ARTICLE
  • Zhao Lu, Mingxin Tao, Qingguang Li, Pan Wu, Shangyi Gu, Wei Gao, Zhihu ...
    原稿種別: ARTICLE
    2022 年 56 巻 2 号 p. 57-73
    発行日: 2022年
    公開日: 2022/03/23
    [早期公開] 公開日: 2022/01/08
    ジャーナル オープンアクセス HTML

    Coalbed water plays an important role in the process of coalbed methane (CBM) generation, storage (adsorption) and production. Because integrated analysis of hydrochemical characteristics and gas geochemical characteristics can offer fresh insights into CBM origin and accumulation, this paper presents an in-depth analysis of the gas geochemistry and hydrogeochemistry characteristics of CBM coproduced water to trace in-situ CBM accumulation in the Tucheng syncline. The main gaseous geochemical parameters (C1/∑C1–5: 0.97~0.99; CHC: 38.3~72.6; CDMI: 5.1~10.5%; δ13C-CH4: –40.7~–43.2‰; δD-CH4: –185.8~–169.2‰; δ13C-CO2: –13.4~–9.3‰) indicate that thermal gas is the primary genetic type, and hydrogeochemical analysis reveals strong traces of microbial activity. Based on carbon isotope fractionation calculation of DIC-CO2-CH4 in CBM and coproduced water, we established a quantitative method for calculating biogenic methane production in CBM coproduced water, finding that production can reach 0.002~0.104 m3/t. Accordingly, we identify a mixed pattern of thermogenic and secondary biogenic CH4. Taking into account the region’s tectonic evolution, we conclude that primary biogenic gas was generated from the Permian to the Early Triassic, thermogenic gas from the Middle Triassic to the Middle Cretaceous, and secondary biogenic gas from the Late Cretaceous to the Quaternary. Secondary biogenic methane’s contribution to the gas pool is limited (20.8%~27.6%), whereas thermogenic methane accounts for 72.4%~79.2%.

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