GEOCHEMICAL JOURNAL
Online ISSN : 1880-5973
Print ISSN : 0016-7002
ISSN-L : 0016-7002
A theoretical attempt to interpret patterns of trace element partitioning in silicate minerals
Hitoshi Kanno
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1977 年 11 巻 3 号 p. 155-160

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Using the conformal solution theory of molten salts (REISS et al., 1962; DAVIS and RICE, 1964; BLANDER, 1967), an attempt was made to interpret the patterns of the partition coefficients of trace elements in silicate minerals as a function of ionic radius. It is shown that the partition coefficient is represented to the zeroth order approximation by the quadratic equation of ionic radius in a “simple” homovalent substitution where host and guest cations are of primarily ionic nature. Pressure effects on the partition coefficient of a trace component are qualitatively discussed with emphasis on the interrelationship of melting points between major and minor components.
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© Geochemical Society of Japan
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