GEOCHEMICAL JOURNAL
Online ISSN : 1880-5973
Print ISSN : 0016-7002
ISSN-L : 0016-7002
Deuterium fractionation between water vapor and hydrogen gas in fumarolic gases
Yoshihiko Mizutani
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1983 年 17 巻 3 号 p. 161-164

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The fumarolic condensate and hydrogen gas samples collected from the Showashinzan, Nasudake, Yakedake and Kuju-Ioyama volcanoes, Japan, have been analyzed for the D/H ratio. A comparison between temperatures for isotopic equilibrium and measured outlet temperatures indicates that in high temperature fumarolic gases the deuterium exchange reaction between water vapor and hydrogen gas is rapid enough to readjust the equilibrium to the outlet temperature of fumaroles. For low temperature fumarolic gases, however, the isotopic temperature refers to equilibrium conditions deep in the fumarole.
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© Geochemical Society of Japan
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