アクリル酸エステル誘導体の共役置換反応を利用した機能高分子合成

抄録

Conjugate substitution reaction of α-(halomethyl) acrylates that proceeds in addition-elimination (S_N2’) mechanism is attractive for polymer chemists, because it undergoes under ambient conditions in quantitative yields to afford α-(substituted methyl) acrylates. In this report, the conjugate substitution reaction is applied to elemental reactions in polymer chemistry, including termination of stereospecific living anionic polymerization, polycondensation, and main chain scission.