In this paper, two supramolecular complexes formed by assembly of bis(Zn-cyclen) complex, organic anion, and copper ion will be reported. Recently, we have isolated a supramolecular complex formed by 4:4:4 self-assembly of bis(Zn-cyclen) complex, cyanuric acid, and copper ion, which was found to catalyze hydrolysis of phosphate monoester. Moreover,we have isolated the 2:2:2 complex of bis(Zn-cyclen) complex, barbital and copper ion, which also exhibits hydrolytic activity of phosphate monoester dianion. .
