IEEJ Transactions on Fundamentals and Materials
Online ISSN : 1347-5533
Print ISSN : 0385-4205
ISSN-L : 0385-4205
Special Issue Paper
Preparation of Dye-Polymer Composite Films by Deposition Polymerization
Hiroaki UsuiShigeo IshibashiAkira KawakamiIkuko KawamataKuniaki TanakaHiroyuki Sone
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2007 Volume 127 Issue 5 Pages 253-260

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Abstract
Dye-doped polymer composite thin films were prepared by physical vapor deposition. The host matrix was polymerized by evaporating n-octadecylacrylate monomer using electron-assisted deposition polymerization method. The guest dye, tris-(8-hydroxyquinoline) aluminum, was introduced into the host matrix by simple coevaporation. The chemical composition can be easily adjusted by controlling the deposition rate of host and guest materials. Thermal stability of the composite films was studied by means of electron microscopy and surface plasmon resonance measurement. It was suggested that the glass transition temperature of the composite film varies with the composition, and the composite films have higher thermal stability compared to the monolithic film of guest dye.
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© 2007 by the Institute of Electrical Engineers of Japan
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