2011 年 131 巻 2 号 p. 102-108
The purpose of this research is to design a structure of membrane electrode assembly (MEA) for reduction of a platinum amount considering with a reaction surface area, a various polarizations and a max power density by changing structure of catalyst layer numbers of MEA. Firstly, an operation of the multi-layered MEA was evaluated. As the result, the reaction surface area increases and the activation polarization decreases as increasing the number of catalyst layers in anode and cathode. In addition, the max power density increases with increasing the reaction surface area and the max power density increases with decreasing the activation polarization. However, a tendency of increasing of the reaction surface area and decreasing of the activation polarization saturated and the max power density decreased in the five-layered MEA. It was thought that flooding occurred by excessive stacking of the catalyst layers on cathode. Therefore, the optimal structure of multi-layered MEA was four-layered structure. In this study, it was clearly understood that multi-layered MEA was effective in increase of reaction surface area of the platinum catalyst, reduction of activation polarization and improvement of maximum output density. In addition, fuel cell module with multi-layered MEA was effective for reducing platinum amount.
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