電気学会論文誌A(基礎・材料・共通部門誌)
Online ISSN : 1347-5533
Print ISSN : 0385-4205
ISSN-L : 0385-4205
論文
化学分析による電気二重層キャパシタの劣化を引き起こす元素の推定
吉玉 拓田島 大輔迫田 達也林 則行湯原 将光宇都宮 隆
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2015 年 135 巻 12 号 p. 792-798

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Chemical analysis was carried out before and after the constant voltage hold test that was an acceleration deterioration examination to clarify deterioration factors of electric double-layer capacitor (EDLC). The results showed that the stress test slightly caused the increase of internal resistance. It was also confirmed that the range of fluorochemicals was formed on the electrode surface for approximately 10 nm in depth using electron spectroscopy for chemical analysis (ESCA). From the chemical analysis of the electrolyte using an inductively coupling plasma emission analyzer (ICP-OES), it was confirmed that the electrolyte included silicone which is one of the ingredient elements of an electrode and that the increase in holding voltage in the stress test decreased the silicone density in the electrolyte.
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© 2015 電気学会
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