New Crystal Structures of p-tert-butylthiacalix [6] arene Complexes with Toluene and Benzyl Alcohol

抄録

It is well known that p-tert-butylthiacalixarenes can make host-guest complexation with organic guestmolecules and metal cations. In order to study crystal structural properties of the titled host molecule withorganic compounds, we tried to make a new crystal of the p-tert-butylthiacalix [6] arene. Fortunately, twonew crystal structures of p-tert-butylthiacalix [6] arenes complexed with toluene and with benzyl alcoholwere obtained. The conformation of the complex with toluene is the cone conformation; on the other hand, the conformation of the complex with benzyl alcohol is 1, 2, 3-alternate.