ISIJ International
Online ISSN : 1347-5460
Print ISSN : 0915-1559
ISSN-L : 0915-1559
Special Issue on "Recent Progress in Inclusion/ Precipitate Engineering"
Thermodynamics of Molten MnS–FeS and CrS–FeS System at 1843 K
Yan LuTakahiro Miki
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2021 年 61 巻 9 号 p. 2345-2354

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Phase equilibria in Fe–Mn–S and Fe–Cr–S ternary systems at 1843 K were investigated experimentally, respectively. The main characteristic of these two systems at 1843 K was confirmed to be a wide miscibility gap between two liquid phases: molten metal alloy phase and molten sulfide phase. Through metal/sulfide equilibrium method, activity of constituents in sulfide phase were determined in Fe–Mn–S and Fe–Cr–S systems separately. The activity curves of constituents in sulfide phase were estimated by utilizing regular solution model.

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© 2021 The Iron and Steel Institute of Japan.

This is an open access article under the terms of the Creative Commons Attribution-NonCommercial-NoDerivs license.
https://creativecommons.org/licenses/by-nc-nd/4.0/
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