To realize carbon dioxide capture and storage(CCS), it is essential to have technology to monitor changes in the subsurface when CO2 is injected deep underground. To this end, the physical properties of rocks in CO2 injection reservoirs must be properly evaluated, and the application of rock physics experiments in a laboratory environment that reproduces the high temperature and pressure environment of the subsurface will contribute to the reliability and effectiveness of monitoring. In this rock physics experiment, P- and S-wave velocities are measured in core samples taken from oil reservoirs during injection of brine, liquid CO2, or supercritical CO2 at controlled effective pressure and temperature. As a result, the P-wave velocity(Vp)was generally in agreement with the logging data, and the velocity variation with effective pressure(Pe)was obtained. The P-wave velocity(Vp)before CO2 injection in the reservoir was estimated based on the experimental equation of P-wave velocity depending on the effective pressure(Pe)during brine injection. The trend of the P-wave velocity(Vp)by the type of injection fluid was also obtained, and the trend of velocity decrease due to CO2 saturation was characterized for the cases of liquid CO2 and supercritical CO2 as pore fluids. For S-wave velocity(Vs), the same velocity variation with effective pressure(Pe)was obtained as for P-wave velocity(Vp). On the other hand, the S-wave velocity(Vs)decreased during supercritical CO2 injection, showing the opposite trend to that assumed by Gassmann’s S-wave velocity(Vs)formula. XRD analysis confirmed the presence of siderite as a cause of the higher velocity. The change in mineral composition after CO2 injection was also observed.