回転電解セルを用いた導電性白金錯体K 1.49 [Pt (C2O4)2］•H2Oの結晶成長-その電気伝導度特性と重力負荷分散の効果について

抄録

Partially oxidised bis (oxalato) Platinate potassium salt was crystallized by 1) aerial oxidation, 2) electrochamical oxidation in a standing still cell, 3) electrochemical oxidation in a rotating cell. The temperature dependence of d.c. electrical conductivitiy was measured for the obtained single crystals and their results were analyzed applying one-dimensional conductor parameters are related with the ways of crystal growth and a reduced interchain interaction is obtained through a rotating electrochamical cell.