Journal of the Ceramic Society of Japan (日本セラミックス協会学術論文誌)
Online ISSN : 1882-1022
Print ISSN : 0914-5400
ISSN-L : 0914-5400
論文
自己組織化する SiO2/TiO2/PMMA ナノ傾斜薄膜の成膜とその低反射特性
高見 和之中島 章渡部 俊也橋本 和仁
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2004 年 112 巻 1303 号 p. 138-142

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Self-organized nanograded SiO2/TiO2/Polymethyl methacrylate (PMMA) thin film was successfully prepared by only one coating from the combination of Tetraethyl orthosilicate (TEOS) and Titanium tetraisopropoxide (TTIP). Sufficient kinetics difference between two alkoxides was an important requirement for the processing of the graded thin film in this process. The film was colorless and transparent due to two gradual interfaces of three layers. The reflectance of the SiO2/TiO2/PMMA graded film was lower than 2% over a wide wavelength range, and this is attributed to the interference of lights reflected from both the SiO2 layer and TiO2 layer. Although further investigation and precise process control are required to further decrease reflectance, this film can be formed using only one coating process and has great potential as a new low reflective coating.

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© 2004 The Ceramic Society of Japan
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