チタニアとアルミナの凝集粒子から調製したチタン酸アルミニウムセラミツクスの粒子配向性

抄録

Aluminum titanate ceramics were fabricated from compacts of aggregated mixture of alumina and titania. The mixture was prepared by precipitation of aluminum hydroxide from aqueous solution of aluminum nitrate, containing rutile powder. After calcination, the mixture was crushed and classified to fractions' 2-5, 5-10, 10-20, 20-47 and 47-77μm sizes. The SEM observation of compacts of the aggregates revealed that the aggregates were not broken by the compaction. The fired bodies of the compacts consisted of oriented aluminum titanate grains. The sizes of the oriented regions were about 4 times larger than the initial aggregate sizes. The reasons for the formation of the oriented grains were considered as follows: the formation of aluminum titanate has low change in free energy, increases elastic energy, and is endothermic. Because of these reasons, grain boundary energy becomes significant in nucleation of aluminum titanate and, therefore, the nucleation occurs epitaxially to result in the oriented texture. The semi-quantitative estimation of change in energies during formation of aluminum titanate agrees with the argument.