Journal of the Ceramic Society of Japan (日本セラミックス協会学術論文誌)
Online ISSN : 1882-1022
Print ISSN : 0914-5400
ISSN-L : 0914-5400
溶融Cuをフラックスとする新しい四元系化合物ErRh2B2C単結晶の合成及び物性
宍戸 統悦葉 金花佐々木 孝彦松本 武彦福田 承生
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1996 年 104 巻 1216 号 p. 1117-1120

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The single crystals of a new quaternary compound ErRh2B2C have been obtained as thin plates in an atmosphere of helium by the flux method using molten copper. The single crystals show golden-colored luster and the maximum size obtained is about 1.0×1.0×0.02mm3. This compound belongs to a tetragonal system and seems to be a derivative of ThCr2Si2 type; lattice parameter: a=0.36848(2)nm, c=1.05520(3)nm, V=1.4327×10-28m3 and Z=2. The electrical resistivity parallel to the a-b plane decreases monotonically with decreasing temperature, but no superconductivity is observed down to 1.5K. The residual resistivity ratio, ρ(273K)/ρ(1.5K), is 1.38. Similar type new compounds of RRh2B2C were obtained for R=La-Er (except Eu and Tm) and Y by arc-melting synthetic method.

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