Journal of the Ceramic Society of Japan (日本セラミックス協会学術論文誌)
Online ISSN : 1882-1022
Print ISSN : 0914-5400
ISSN-L : 0914-5400
各種酸化物粒子のζ電位と帯電機構
高山 佳典根岸 秀之中村 聡小浦 延幸井手本 康山口 文雄
著者情報
ジャーナル フリー

1999 年 107 巻 1242 号 p. 119-122

詳細
抄録

The charging behavior of various oxide particles was investigated using the zeta potential, which is affected by the electronegativity of the metal ion in an oxide and the properties of the solvents. Acetone, methylethylketone, cyclohexanone, ethanol (EtOH), 1-propanol (1-PrOH) and 1-butanol (1-BuOH) were used for the bath. In the case of the I2-added ketone bath, the H+ ion concentration increased with increasing I2 content. The zeta potential of the various oxide particles was changed to positive. The zeta potential of the oxides was large in the high H+ ion concentration bath. Accordingly, the positive charged oxide particles were attributed to the adsorption of H+ ion onto the particles. In the case of alcohol, included H2O generates H+ and OH- by electrolytic dissociation. Therefore, the zeta potential becomes large in the case when the electronegativity of the metal ion in oxide is low, and the H+ ion behaves as a potential determining ion.

著者関連情報
© The Ceramic Society of Japan
前の記事 次の記事
feedback
Top