Journal of the Ceramic Society of Japan (日本セラミックス協会学術論文誌)
Online ISSN : 1882-1022
Print ISSN : 0914-5400
ISSN-L : 0914-5400
超急冷法で調製したLi2O-K2O-Al2O3-SiO2-F系ガラスの結晶化
河合 進元山 宗之
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1990 年 98 巻 1138 号 p. 604-606

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The crystallization process of the rapidly quenched glasses in the system Li2O-K2O-Al2O3-SiO2-F has been investigated. Batches of the lepidolite composition were melted at 1773K for 10 minutes and quenched with a twin roller aparatus. Lepidolite and β-eucryptite were precipitated at 773K and 873K, respectively. However, it was requisited to keep the glass at 773K for more than 1 hour for the precipitation of lepidolite. The thermal conductivity of the glass-ceramics heated at 773K for 1hour and then at 973K for 2hours was larger than fluorphrogopite glass-ceramics, and its thermal expansion coefficient and dielectric properties were similar to those of fluorphrogopite glass-ceramics.
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