Journal of the Ceramic Society of Japan
Online ISSN : 1348-6535
Print ISSN : 1882-0743
ISSN-L : 1348-6535
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Hydrothermal synthesis of a new perovskite-type bismuth oxide: Ba0.96Bi0.86O2.59(OH)0.41
Hong JIANGNobuhiro KUMADAYoshinori YONESAKITakahiro TAKEINobukazu KINOMURA
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2009 年 117 巻 1362 号 p. 214-216

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A new perovskite-type oxide, Ba0.96Bi0.86O2.59(OH)0.41 was prepared by low temperature hydrothermal reaction using NaBiO3·nH2O and Ba(OH)2·8H2O as starting materials. The crystal structure of this compound was refined by single crystal X-ray diffraction data, and the structure refinement with the space group Pm3m (#221) led to Rw = 0.035 and R = 0.054 for all reflections. This compound had the perovskite-type structure with the cubic cell of a = 4.2995(5) Å. The magnetic susceptibility of this compound exhibited no superconductive behavior down to 4 K.
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© 2009 The Ceramic Society of Japan
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