2011 年 119 巻 1390 号 p. 544-547
Melt spun silicone resin fiber with a diameter of 14 µm was exposed to TiCl4 vapor with flowing nitrogen at room temperature or 40°C. During the exposure, TiCl4 was incorporated in the resin network with formation of cross-links. After standing in ambience for 24 h and pyrolysis in an air flow, SiO2–TiO2 fibers were obtained in a yield of 75–80%. Ti/Si content can be controlled by adjusting the curing time and temperature. TiO2 existed as nano particles or aggregated large particles, which were strongly attached on the fiber body. Analysis of 2-propanol degradation by the fiber under UV light suggested the existence of photocatalytic activity.
