2013 年 121 巻 1409 号 p. 109-112
Needle- and plate-like NaTaO3 have been synthesized at low temperatures (<500°C) in three steps by a molten NaOH method. First, Na3TaO4 precursor was synthesized by the reaction of Ta2O5 with a molten NaOH at 450°C for 50 h in air. Then, Na3TaO3 precursor reacted with H2O to form needle-like Na7(H3O)Ta6O19·14H2O and plate-like Na8Ta6O19·24H2O intermediates in the process to wash the excess NaOH in the crucible with H2O. The needle-like Na7(H3O)Ta6O19·14H2O was the major product. Then, these intermediates transformed to NaTaO3 through dehydrate intermediates by heating at above 500°C. The obtained NaTaO3 had needle- and plate-like morphology with a perovskite structure.