材料と環境
Online ISSN : 1881-9664
Print ISSN : 0917-0480
ISSN-L : 0917-0480
80℃の3% NaCl水溶液中における高純度オーステナイトステンレス鋼のすきま腐食溶解挙動に及ぼす合金元素の影響
チェン ピーター哲生篠原 正辻川 茂男
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1996 年 45 巻 7 号 p. 420-426

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Effects of P, Si, Mn, Cu and Al on the dissolution behavior of crevice corrosion were studied by using high purity 18Cr-14Ni and 14Cr-16Ni steels with systematic variations in alloying elements in 3% NaCl solution at 80°C via the moire method. It was found that while no major alloying effects were found in the initial stage of crevice corrosion, alloying does influence the behavior of crevice dissolution in the stationary growth stage of corrosion development. The dissolution rate of steady growth stage, VII, increases with increasing content of phosphorous at a fixed electrode potential, while it is found to remain constant at the repassivation potential for crevice corrosion which becomes increasingly noble with increasing phosphorus content.
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