材料と環境
Online ISSN : 1881-9664
Print ISSN : 0917-0480
ISSN-L : 0917-0480
TiAl金属間化合物の高温酸化に及ぼすAlの溶融塩電析処理による効果
福本 倫久原 基長瀧 俊郎
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2002 年 51 巻 11 号 p. 510-515

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An Al deposit layer on TiAl substrate was formed by electrodepositing Al and alloying it with TiAl in molten salt. Electrolysis of Al was conducted using a potentiostatic polarization method at constant potentials in an equimolar NaCl-KCl melt containing 3.5mol% AlF3 at 1023K. The mass of electrodeposited material increased with decreasing in polarization potential. Deposits formed at -1.3- -1.6V (vs. Ag/Ag+ (0.1)) built up a homogeneous layer. These deposits consisted of TiAl3. TiAl covered by the electrodeposit layer was more resistant than bare TiAl to high temperature oxidation.
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