873KにおけるNi基超合金の耐硫化性に及ぼすTiおよびAl添加量の影響
2002 年 51 巻 8 号 p. 356-360
詳細
2002 年 51 巻 8 号 p. 356-360
Sulfidation properties of the alloys that include Ti of 1.5 to 2.0mass% and Al of 2.0 to 3.0mass% with basic composition of AISI 685, which is used as a rotor material of FCC power recovery turbine, were investigated at 873K in an atmosphere of PS2=10-0.5 and PO2=10-18.5Pa. Sulfidation amount was decreased with increasing the Al content in the alloys of including the same level of Ti. The 1.5Ti-3.0Al, 2.0Ti-3.0Al and 1.5Ti-3.5Al alloys (mass%) showed the mass gain and scale thickness less than half of AISI 685. This is due to the diffusion control of metal ions and gases by the Al-rich oxide and/or sulfide in the innermost scale layer.
