低温工学
Online ISSN : 1880-0408
Print ISSN : 0389-2441
ISSN-L : 0389-2441
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V3Ga 超伝導線材における高濃度Ga 化合物を用いた新プロセスの開発
菱沼 良光菊池 章弘飯嶋 安男村上 聡川畑 常眞松田 健二谷口 博康竹内 孝夫
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2012 年 47 巻 8 号 p. 495-502

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Vanadium-gallium (V 3 Ga) superconducting wire is an “old superconducting material", and was one of the original materials famed for the “Cu additive effect" that was extended to the “Bronze route process". The “Cu additive effect" in A15 phase compounds promotes A15 phase formation via diffusion reaction. The V 3 Ga compound has interesting properties for an advanced magnetic confinement fusion reactor beyond ITER. The decay time of induced radio activity for V 3Ga is within 1 month and is much shorter than that of Nb-based superconductors such as Nb-Ti, Nb 3 Sn and Nb 3 Al. We thought that V 3 Ga wire was one of the candidate materials for “Low activation superconducting wires" to operate under a neutron irradiation environment such as in a fusion reactor. However, the Jc and Hc2 properties of V 3 Ga wire are insufficient to realize this feature in fusion application. In previous studies, V 3 Ga wire was mainly investigated in term of the “Diffusion process" between Cu-Ga within a 20 at% Ga composition and V filament. For further Jc and Hc2 enhancements, we investigated the fabrication of V 3 Ga compound multi-filamentary wires using a high Ga content Cu-Ga compound applying the powder-in-tube process. Thicker V 3 Ga layers formed along the boundary between the Cu-Ga powder filaments and V matrix, and the volume fraction of V 3 Ga increased compared to previous diffusion processed samples. We also found that the new route PIT process using a high Ga content Cu-Ga compound is effective for improving the superconducting properties of the V 3 Ga compound wire.
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© 2012 公益社団法人 低温工学・超電導学会 (旧 社団法人 低温工学協会)
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