1979 年 14 巻 5 号 p. 226-230
The Nb3Sn layer was formed at the interface between Nb and Sn-Cu alloy for a short reaction time near the temperature of 700°C. In case that the layer thickness of the Cu-Sn alloy on the surface of Nb is thicker than several μm, the Cu content of Cu-Sn alloy should be above 30 at.% to produce the Nb3Sn layer for a short reaction time at this temperature. When the layer thickness of Cu-Sn alloy plated initially is thinner than 1μm, even a Cu-Sn alloy with a less than 10 at.% Cu can produce the Nb3Sn by utilizing the variation of Cu concentration during reaction. The Nb3Sn layer having Tc of 18.05 with ΔTc of 0.05K was prepared from about 1μm thickness of 20 at.% Cu-Sn alloy reacted at the temperature of 720°C for 24h.