環境化学
Online ISSN : 1882-5818
Print ISSN : 0917-2408
ISSN-L : 0917-2408
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網羅的自動同定定量システム(AIQS)を用いた油流出事故時における土壌汚染対策の有効性の検証
西牟田 昂門上 希和夫宮脇 崇松尾 友貴古賀 夕貴樋口 汰樹龍田 典子上野 大介
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2020 年 30 巻 p. 57-65

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Oil spill accident from steel mill was caused by flood in August 2019 in Saga Prefecture, Japan. As the disaster response, spilled oil which was floating on the flood water was recovered by oil absorption sheets. It was hypothesized that soil contamination by spilled oil might be avoided if the oil could be recovered before it contacted to soil. The paddy soil samples collected in oil contaminated area (clean up with oil absorption sheets, n=3), control areas (n=2), and used quench oil (spilled oil from steel mill) were employed for chemicals analysis. The analytical technique of Automated Identification and Quantification Systems with gas chromatography mass spectrometry (AIQS-GC) was applied for Comprehensive Target Analysis (CTA). As the result of chemical analysis, sterols, alkanes, PAHs (including native- and methylated-PAHs), and other compounds were detected in paddy soil samples. Only alkanes and PAHs were detected from used quench oil. No clear differences were found on alkanes and PAHs concentrations between paddy soils collected in oil contaminated area and control area. On the other hand, contribution of chemicals detected in paddy soils and used quench oil were clearly different. These results indicate that soil contamination by spilled oil could be avoided by the recovering of spilled oil using oil absorption sheets during it was floating on the flood water.

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