主催: 社団法人 日本エネルギー学会
共催: 社団法人 化学工学会 エネルギー開発特別研究会
会議名: 第35回石炭科学会議
回次: 35
開催地: つくば
開催日: 1998/11/19 - 1998/11/20
p. 31-34
Illinois #6 coal was treated using trifluoromethanesulfonic acid (TFMS) in the presence of isopentane and methylcyclopentane at 120℃ for 3h. Thus the extraction yield in THE was increased to 80-90%. The THF solubilized coal was then hydrogenated over a Ru/activated carbon catalyst at 120℃ for 48h under a hydrogen pressure of 10MPa. The liquid product was obtained after the solvent removal, and the H/C atomic ratio increased from 0.88 to 1.52 by the reaction. The increase in pyrolysis reactivity of the hydrogenated liquid was due to hydrogenation of aromatic rings.