石炭科学会議発表論文集
Online ISSN : 2423-8309
Print ISSN : 2423-8295
ISSN-L : 2423-8295
第52回石炭科学会議
セッションID: No.11
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No.11 新しい炭素-酸化物複合担体担持CoおよびFe触媒による溶媒存在下でのフィッシャー-トロプシュ合成(ガス化・燃焼・液化(2))
前嶋 悠佑那須 弘行橋本 忠範石原 篤
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会議録・要旨集 フリー

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Novel carbon-oxide composite supported Co and Fe catalysts for Fischer-Tropsch synthesis were prepared by the sol-gel method. Silica, alumina and zirconia were used as oxide. Futher PEG was used as carbon source in catalysts. In the sol-gel method, prepared gels were calcinated under N_2 atmosphere. After H_2 reduction at 360℃, the reaction was performed under the conditions, temperature 280-340℃, syngas (H_2: 66%, CO: 33%, Ar: 1%), and decalin 10ml/h. The activity greatly changed by a kind of oxide in the presence of solvent. Conversions of CO increased in the order alumina <silica <zirconia.

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