石炭科学会議発表論文集
Online ISSN : 2423-8309
Print ISSN : 2423-8295
ISSN-L : 2423-8295
第55回石炭科学会議
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熱分解・コークス(2),重質油(1)
No.1-23 RDS/RFCCプロセスにおける重質油中の多環芳香族の接触分解
嶋田 五百里鵜野 千亜樹長田 光正福長 博高橋 伸英高塚 透
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p. 46-47

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Catalytic cracking of 3-ring polycylcic aromatic hydrocarbons (PAHs) with hydrogen donors (naphthenes and paraffins) was investigated using residue fluid catalytic cracking (RFCC) catalysts with high hydrogen transfer activity. 3-ring PAHs were partly hydrogenated by accepting hydrogen species released by hydrogen donors, and then converted to monocyclic aromatic hydrocarbons (MAHs) by consecutive cracking of the saturated rings. The rate-determining step of the 3-ring conversion was the cracking of the saturated rings. These results suggest that the hydrogen distribution among the reactants and products in RFCC process is important for optimizing the heavy oil processing.

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