1969 年 33 巻 9 号 p. 1030-1035
The precipitation behaviour of V4C3 and the structural change in Mn-Cr-V type austenitic steel with a chemical composition of 0.44%C, 17.40%Mn, 12.15%Cr and 2.37%V have been studied by measuring the changes in dilatation and hardness and by transmission electron microscope observations. The results obtained are as follows:
(1) The precipitated carbide which brings about a remarkable hardening and dilatation change is spherical V4C3 only.
(2) The strain field caused by the coherency between V4C3 and the matrix is released when the particle size grows up to a diameter of 150∼160 Å, resulting in contraction and the hardness decrease of the austenic steel. This suggests that the coherency between V4C3 and the matrix plays an important role in the strengthening of austenitic steel in the Mn-Cr-V system.