起電力法を用いた高温領域におけるNiO, Cu2OおよびCoOの標準生成自由エネルギーの測定
1977 年 41 巻 8 号 p. 803-808
詳細
1977 年 41 巻 8 号 p. 803-808
Emf measurements of the following galvanic cells with the solid electrolyte (ZrO2+CaO) were carried out to determine the standard molar free energies of formation of NiO (s), Cu2O (s, l) and CoO (s) from their solid and liquid metals and oxygen gas:
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oindentEmf differences between Cell(I) and Cell(II), Cell(I) and Cell(III) were compared with emf of the following cells:
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oindentThe results were expressed by the following equations:
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oindentThey compared with previously reported values.
