日本金属学会誌
Online ISSN : 1880-6880
Print ISSN : 0021-4876
ISSN-L : 0021-4876
高周波熱プラズマで処理したチタンカーバイド粉末のAl2O3-TiC複合セラミックスヘの応用
石垣 隆正佐藤 忠夫田中 順三目 義雄守吉 佑介
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1999 年 63 巻 1 号 p. 82-89

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In order to investigate the influence of plasma treatment on the powder properties, titanium carbide powder with an average particle size of 1.35 μm was modified by the in-flight induction plasma treatment generated at the plate power of 45 kW and reactor pressure of 26.7 kPa. The treatment in Ar-H2 induced the formation of carbon-site vacancies. The tail injection of Ar-NH3 to the Ar-H2 plasma resulted in the partial substitution of carbon by nitrogen. Also, the treatment in Ar-N2 plasma gave rise to the partial nitridation. A large amount of oxygen incorporated into the plasma-treated powders stored in air. The original and plasma-treated powders were dispersed in an alumina matrix, and the pressureless sintering of Al2O3-TiC composites was tried to elucidate the influence of plasma modification. The composites with the dispersion of plasma-treated titanium carbide powders showed an increase in sintered density.

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