1983 年 7 巻 2 号 p. 79-82
Garnet LPE films containing bismuth which support 1 μm bubbles have been grown on (111) GGG substrates. Gallium substituted garnets, such as YSmTmBiGa, YTmBiGa and LaSmLuGa films, have good properties at room temperature, e.g., low damping, small collapse field (Hco1) and small crystalline anisotropy constant (|K1|). These films are not suitable for bubble propagation at higher temperatures because of too low Curie temperature (Tc) after ion implantation. On the other hand, calcium germanium substituted garnets, such as GdSmTmBiCaGe and YSmTmBiCaGe have higher Tc and larger negative magnetostriction coefficient, λ111. However, Q factor or characteristic length (l) is restricted by small Sm3+ contents in these films. By substituting Si4+, instead of Ge4+, we can get much room to adjust the film properties. GdSmLuBiCaSi films have zero temperature dependence of Hco1. Temperature coefficient of Hco1 for YGdSmLuBiCaSi is −0.2%/°C Atomic compositions for BiCaSi substituted films are analyzed. Y3+ and Lu3+ are partially substituted into a-site. Distribution coefficients for Y3+, Gd3+, Sm3+ and Lu3+ are estimated.