抄録
Production conditions of ThO2 sols suitable for gelling into crackfree microspheres in an external gelation process were studied. The sols were prepared under pH control and colloid size distributions of the resulting sols were determined. The gelation was carried out by using hexone as a drop formation medium and ammonia as a gelling agent. The crackfree gelation was achieved by the use of ThO2 sols produced under favorable pH, which were large in colloid size and high in colloid fraction. "Preneutralization" preceding the pH control is also important for the good sols. Analyzing the colloid fraction, colloid size and crystallite size of sol, it was found that, under the favorable pH, colloid nuclei generating at early stages grow in the form of single-crystals with their number kept constant and, after cooling, they exist as polycrystalline colloids. The mechanism of cracking is also discussed.
