Journal of Nutritional Science and Vitaminology
Online ISSN : 1881-7742
Print ISSN : 0301-4800
ISSN-L : 0301-4800
OXIDATION PRODUCTS OF N-METHYL-2, 2, 7, 8-TETRAMETHYL-6-AMINO-CHROMAN, A MODEL COMPOUND OF N-METHYL-γ-TOCOPHER-AMINE WITH POTASSIUM FERRICYANIDE
五十嵐 脩
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ジャーナル フリー

1977 年 23 巻 3 号 p. 169-178

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抄録
N-Methyl-2, 2, 7, 8-tetramethyl-6-amino-chroman, a model compound of N-methyl-γ-tocopheramine, was submitted to an oxidation study with alkaline potassium ferricyanide. As oxidative products, 2, 2, 7, 8-tetramethyl-6-amino-chroman and dimeric (VI) were identified. Also, a trace of compound C which might be a azochroman was detected. It was concluded that an N radical formation is necessary to take the role of a biological antioxidant of N-methyl-γ-tocopheramine.
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